NMR Detection of Oxygen Isotopes in Ti02 Single Crystal*

نویسندگان

  • M. Tanigaki
  • S. Takeda
  • K. Matsuta
  • H. Akai
  • K. Sato
  • T. Miyake
  • Y. Maruyama
  • A. Morishita
  • M. Fukuda
چکیده

We studied the electric quadrupole interactions of Oxygen isotopes in a T i 0 2 single crystal. For l 3 0 and 1 9 0 nuclei, quadrupole coupling constants were measured by the /3-NMR technique, and for the 1 7 0 nucleus the FT-NMR technique was utilized. We synthesized a T i0 2 single crystal which was enriched in 1 7 0 up to 5 atom % to observe NMR signals without any perturbations from impurities. Using the known quadrupole moment of l 7 0 , EFGs at an O site in T i 0 2 and the quadrupole moments of 1 3 0 and l 9 0 were determined.

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تاریخ انتشار 2012